Optical constants of As2S3 (Arsenic trisulfide)
Synowicki and Tiwald 2004: n,k 0.13–17 µm
Complex refractive index (n+ik)
Derived optical constants
Comments
Data generated from oscillator model.
References
R.A. Synowicki and T. E. Tiwald.
Optical properties of bulk c-ZrO2, c-MgO and a-As2S3 determined by variable angle spectroscopic ellipsometry.
Thin Solid Films 455-456, 248-255 (2004)
Calculation scripts (Python):
Synowicki 2004 - As2S3 -- UV.py
Synowicki 2004 - Aux funcs.py
Data
Additional information
About Arsenic trisulfide
As2S3, also known as arsenic trisulfide, exists in both crystalline and amorphous forms. The crystalline form is commonly referred to as orpiment and occurs naturally as a mineral. However, in optical and photonic applications, the amorphous or glassy form of As2S3 is often preferred. This chalcogenide glass features a broad transmission window that extends from the visible to the mid-infrared spectral regions, and it is known for its high nonlinear optical coefficients. The amorphous structure allows for the material to be easily molded, drawn into fibers, or deposited as thin films, making it highly versatile for a variety of optoelectronic applications. It also offers the advantage of strong light confinement due to its high refractive index. However, users should exercise caution as the material contains toxic arsenic, and its photosensitive nature necessitates consideration for stability under light exposure. Whether in its crystalline or amorphous state, As2S3 remains a material of significant interest for both its unique optical properties and its potential in emerging technologies. Mineral: Orpiment
Other names and variations:- As2S3
- Arsenic(III) sulfide
- Diarsenic trisulfide
- Arsenic trisulphide
- Arsenic(III) sulphide
- Diarsenic trisulphide
- Orpiment